全文获取类型
收费全文 | 4605篇 |
免费 | 579篇 |
国内免费 | 159篇 |
专业分类
化学 | 1035篇 |
晶体学 | 1篇 |
力学 | 321篇 |
综合类 | 201篇 |
数学 | 2862篇 |
物理学 | 923篇 |
出版年
2023年 | 37篇 |
2022年 | 137篇 |
2021年 | 202篇 |
2020年 | 149篇 |
2019年 | 117篇 |
2018年 | 122篇 |
2017年 | 240篇 |
2016年 | 272篇 |
2015年 | 168篇 |
2014年 | 353篇 |
2013年 | 261篇 |
2012年 | 293篇 |
2011年 | 285篇 |
2010年 | 234篇 |
2009年 | 251篇 |
2008年 | 238篇 |
2007年 | 248篇 |
2006年 | 235篇 |
2005年 | 245篇 |
2004年 | 198篇 |
2003年 | 158篇 |
2002年 | 126篇 |
2001年 | 88篇 |
2000年 | 82篇 |
1999年 | 66篇 |
1998年 | 85篇 |
1997年 | 62篇 |
1996年 | 53篇 |
1995年 | 48篇 |
1994年 | 33篇 |
1993年 | 31篇 |
1992年 | 32篇 |
1991年 | 27篇 |
1990年 | 14篇 |
1989年 | 19篇 |
1988年 | 16篇 |
1987年 | 8篇 |
1986年 | 10篇 |
1985年 | 27篇 |
1984年 | 13篇 |
1983年 | 10篇 |
1982年 | 12篇 |
1981年 | 13篇 |
1980年 | 8篇 |
1979年 | 7篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1959年 | 2篇 |
排序方式: 共有5343条查询结果,搜索用时 31 毫秒
1.
We prove that the resultant of two “sufficiently generic” bivariate polynomials over a finite field can be computed in quasi-linear expected time, using a randomized algorithm of Las Vegas type. A similar complexity bound is proved for the computation of the lexicographical Gröbner basis for the ideal generated by the two polynomials. 相似文献
3.
4.
Among all the bio‐metals, zinc and copper derivatives of ONS donor thiosemicarbazone have aroused great interest because of their potential biological applications. Multisubstituted thiosemicarbazone ligand H2dspt (3,5‐dichlorosalicylaldehyde‐N4‐phenylthiosemicarbazone) derived new ternary complexes like [Zn(dspt)(phen)]?DMF ( 1 ) and [Cu(dspt)(phen)]?DMF ( 2 ), and another thiosemicarbazone, H2dsct (3,5‐dichlorosalicylaldehyde‐N4‐cyclohexylthiosemicarbazone), derived [Cu(dsct)(bipy)]?DMF ( 3 ). These complexes have been characterized by elemental analysis (CHNS), Fourier transform infrared (FT‐IR), ultraviolet–visible (UV–Vis) and proton nuclear magnetic resonance (1H‐NMR) spectra. The structures of the complexes were obtained by single‐crystal X‐ray diffraction analysis. Compounds 1 and 2 got crystallized in the monoclinic P21/c space group. The complexes showed interesting supramolecular interaction, which in turn stabilizes the complexes. The ground state electronic configurations of the complexes were studied using the B3LYP/LANL2DZ basis set, and ESP plots of complexes were investigated. The interaction of the complexes with calf thymus DNA (CT‐DNA) was studied using absorption and fluorescence spectroscopic methods. A UV study of the interaction of the complexes with calf thymus DNA (CT‐DNA) has shown that the complexes can effectively bind to CT‐DNA, and [Cu(dspt)(phen)]·DMF ( 2 ) exhibited the highest binding constant to CT‐DNA (Kb = 3.7 × 104). Fluorescence spectral studies also indicated that Complex 2 binds relatively stronger with CT DNA through intercalative mode, exhibiting higher binding constant (Kq = 4.7 × 105). The DNA cleavage result showed that the complexes are capable of cleaving the DNA without the help of any external agent. Molecular docking studies were carried out to understand the binding of complexes with the molecular target DNA. Complex 2 exhibited the highest cytotoxicity against human breast cancer cell line MD‐MBA‐231 (IC50 = 23.93 μg/mL) as compared to Complex 1 (IC50 = 44.40 μg/mL) . 相似文献
5.
6.
为弥补茶叶品质感官审评存在的缺陷,利用计算机视觉技术对茶叶品质进行快速无损评价研究。以碧螺春绿茶为对象,依据专家感官审评结果,将茶样分成4个等级;采用中值滤波及拉普拉斯算子对茶样图像进行预处理,并提取预处理后的茶样图像的颜色特征和纹理特征以表征茶叶图像的外形特征,利用随机森林算法对茶叶外形特征属性进行重要性排序;筛选出重要性较大的特征及随机森林算法中最优的决策树棵数建立感官评价模型,并与建立的支持向量机(SVM)模型性能相比较。结果表明:色调均值、色调标准差、绿体均值、平均灰度级、饱和度均值、红体均值、饱和度标准差、亮度均值、一致性等9个特征属性的重要性较大,且与感官审评特征描述结果相一致;当采用优选出的9个重要性较大的特征及决策数棵数为500时,建立的模型性能最优,模型总体判别率为95.75%,Kappa系数为0.933,OOB误差为5%,较SVM模型分别提高了3.5%,0.066,优选的9个重要性较大的图像特征与感官审评特征描述相一致。研究表明:利用随机森林方法筛选出对茶叶外形特征属性贡献最大的少数几个特征建立模型,模型性能就能达到很好的识别效果,模型得到简化,同时模型精度和稳定性都高于其他方法。 相似文献
7.
设计了以柴油中饱和烃含量及碳数分布测定、聚丙烯酸高级醇酯(PTA)的合成与纯化、PTA的红外表征与分子量测定、PTA降凝性能评价等4个模块组成的综合实验,作为化工专业实验的考核及成绩评定平台。这种考核方式将过程考核与结果考核融合,将笔试、操作、设计融合,可以全面准确地考核学生的有机合成、仪器分析等基础实验技能,同时考核综述、数据处理、实验设计等综合实验能力和实验室工作素质。此外,还能够有效训练学生的学习能力、解决问题能力、实践能力和创新能力,并促进了实验教学水平提高。 相似文献
8.
Randall Claywell Laszlo Nadai Imre Felde Sina Ardabili Amirhosein Mosavi 《Entropy (Basel, Switzerland)》2020,22(11)
The accurate prediction of the solar diffuse fraction (DF), sometimes called the diffuse ratio, is an important topic for solar energy research. In the present study, the current state of Diffuse irradiance research is discussed and then three robust, machine learning (ML) models are examined using a large dataset (almost eight years) of hourly readings from Almeria, Spain. The ML models used herein, are a hybrid adaptive network-based fuzzy inference system (ANFIS), a single multi-layer perceptron (MLP) and a hybrid multi-layer perceptron grey wolf optimizer (MLP-GWO). These models were evaluated for their predictive precision, using various solar and DF irradiance data, from Spain. The results were then evaluated using frequently used evaluation criteria, the mean absolute error (MAE), mean error (ME) and the root mean square error (RMSE). The results showed that the MLP-GWO model, followed by the ANFIS model, provided a higher performance in both the training and the testing procedures. 相似文献
9.
古镇作为集自然景观与人文景观一体的景区,具有丰富的声音类型。本研究以大研古镇为例,通过实地调研探究不同声音偏好的游客对古镇声景观的主观评价差异。基于游客的声音偏好,将游客分为偏爱自然声和偏爱人工声两大类。通过因子分析提取游客声景观主观评价的5个主因子:大小、音质、效价、偏好和唤醒。进一步分析发现,这5个因子具有一定的层级性,其中从大小到唤醒代表声景观评价从声音的物理属性向声音的联想评价逐级提升。其中在低层级评价(大小、音质)中,偏好自然声的游客和偏好人工声的游客无显著差异,低层级评价具有稳定性;而在高层级评价(效价、偏好和唤醒)中,偏好人工声的游客更关注古镇声景观的淳朴性和遗产性。因此,游客对声景观的主观评价可视为一种指标,判断景区声景所处的评价阶段,从而为景区声景观改善提供更有针对性的建议。 相似文献
10.
Shi Qiu Wen-zhi Yang Xiao-jian Shi Chang-liang YaoMin Yang Xuan LiuBao-hong Jiang Wan-ying Wu De-an Guo 《Analytica chimica acta》2015
Exploration of new natural compounds is of vital significance for drug discovery and development. The conventional approaches by systematic phytochemical isolation are low-efficiency and consume masses of organic solvent. This study presents an integrated strategy that combines offline comprehensive two-dimensional liquid chromatography, hybrid linear ion-trap/Orbitrap mass spectrometry, and NMR analysis (2D LC/LTQ-Orbitrap-MS/NMR), aimed to establish a green protocol for the efficient discovery of new natural molecules. A comprehensive chemical analysis of the total ginsenosides of stems and leaves of Panax ginseng (SLP), a cardiovascular disease medicine, was performed following this strategy. An offline 2D LC system was constructed with an orthogonality of 0.79 and a practical peak capacity of 11,000. The much greener UHPLC separation and LTQ-Orbitrap-MS detection by data-dependent high-energy C-trap dissociation (HCD)/dynamic exclusion were employed for separation and characterization of ginsenosides from thirteen fractionated SLP samples. Consequently, a total of 646 ginsenosides were characterized, and 427 have not been isolated from the genus of Panax L. The ginsenosides identified from SLP exhibited distinct sapogenin diversity and molecular isomerism. NMR analysis was finally employed to verify and offer complementary structural information to MS-oriented characterization. The established 2D LC/LTQ-Orbitrap-MS/NMR approach outperforms the conventional approaches in respect of significantly improved efficiency, much less use of drug materials and organic solvent. The integrated strategy enables a deep investigation on the therapeutic basis of an herbal medicine, and facilitates new compounds discovery in an efficient and environmentally friendly manner as well. 相似文献